Star from Star vs. the Forces of Evil

And Meliodas from the Seven Deadly Sins

O and Tamaki Suoh from Ouran Highschool Host Club

I'm gonna list a few non-blue-eyed blonde characters.
Sophie from School of good and evil.
Bakugo Katsuki from BNHA
Adrien Agreste from Miraculous
Himiko Toga from BNHA
And I think Anabeth (I think that's her name and I don't think she has blue eyes, I don't know, I've never read Percy Jackson) from Percy Jackson.
It was hard to name 5-

Ash Lynx is a character from Banana Fish, I think he has green eyes.